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柠檬酸辅助合成NaLa(MoO4)2:Eu3+及其发光性能

刘运 高伟萍 史晓磊 罗超 左浩强

陕西科技大学学报(自然科学版)Issue(5):40-45,6.
陕西科技大学学报(自然科学版)Issue(5):40-45,6.

柠檬酸辅助合成NaLa(MoO4)2:Eu3+及其发光性能

Citric acid-assisted synthesis of NaLa(MoO4)2:Eu3+phosphors and luminescence properties

刘运 1高伟萍 1史晓磊 1罗超 1左浩强1

作者信息

  • 1. 陕西科技大学理学院,陕西西安 710021
  • 折叠

摘要

Abstract

Eu3+‐doped NaLa (MoO4 )2 red phosphors were prepared via a citric acid‐assisted hydrothermal process and the samples were annealed at 600 ℃ for two hours .The asprepared products were characterized by X‐ray diffraction (XRD) ,field emission‐scanning electron mi‐croscopy (FE‐SEM ) and photoluminescence (PL ) ,respectively .The results demonstrated that the obtained NaLa(MoO4 )2 :Eu3+ phosphors are pure tetragonal phase of which the e‐mission intensity enhanced with the increasing of Eu3+ doping concentration .Moreover ,the charge transfer band shift to the red with broadening of its peak ,and the optimum Eu3+ do‐ping concentration for obtaining maximum emission intensity was confirmed to be 50% .In addition ,the phosphor can be effectively excited by 280 nm ,395 nm and 465 nm .All com‐pounds exhibit strong luminescence emissions of 5 D0 → 7 F2 transition at 617 nm .Chromaticity coordinates of NaLa(MoO4 )2 :Eu3+ are stable and fit well with the standard red color coordi‐nate .The results indicate that NaLa(MoO4 )2 :Eu3+ is a wide used red‐emitting phosphors with good stability .

关键词

NaLa(MoO4)2:Eu3+/柠檬酸/水热合成/发光性能

Key words

NaLa(MoO4 )2:Eu3+/citric acid/hydrothermal synthesis/luminescence proper-ties

引用本文复制引用

刘运,高伟萍,史晓磊,罗超,左浩强..柠檬酸辅助合成NaLa(MoO4)2:Eu3+及其发光性能[J].陕西科技大学学报(自然科学版),2015,(5):40-45,6.

基金项目

国家自然科学基金项目(51272148);陕西省科技厅自然科学基础研究计划项目 ()

陕西科技大学学报(自然科学版)

OACSTPCD

2096-398X

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