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含氟聚丙烯酸酯细乳液的制备及性能

张文博 马建中 高党鸽 张雷

陕西科技大学学报(自然科学版)Issue(6):23-26,4.
陕西科技大学学报(自然科学版)Issue(6):23-26,4.

含氟聚丙烯酸酯细乳液的制备及性能

Synthesis and properties of fluorine-containing polyacrylate miniemulsion

张文博 1马建中 1高党鸽 2张雷1

作者信息

  • 1. 陕西科技大学资源与环境学院,陕西西安 710021
  • 2. 陕西农产品加工技术研究院,陕西西安710021
  • 折叠

摘要

Abstract

A waterborne polyacrylate miniemulsion was synthesized by miniemulsion polymer‐ization with methyl methacrylate ,butyl acrylate ,hexafluorobutyl acrylate (HFA) .The effect of HFA content on monomer conversion rate ,particle size ,water absorption ,contact angle , sanitation properties and rubbing fastness of coated leather were studied and the results indi‐cate that the properties of polyacrylate miniemulsion were improved by HFA .As the HFA content increased ,monomer conversion rate remained at around 97% ,latex particle size in‐creased ,contact angle increased and then kept constant .The film water absorption reached the minimum 6 .84% when the HFA content was 0 .5% .The dry and wet fastnesses of the coated leather were improved by 1 degree without compromising the sanitation properties .

关键词

含氟聚丙烯酸酯/细乳液/涂饰/耐水性

Key words

fluorine-containing polyacrylate/miniemulsion/leather finishing/water resist-ance

分类

轻工业

引用本文复制引用

张文博,马建中,高党鸽,张雷..含氟聚丙烯酸酯细乳液的制备及性能[J].陕西科技大学学报(自然科学版),2015,(6):23-26,4.

基金项目

陕西省科技厅科技统筹创新工程计划项目(2015KTCL01-11);陕西省科技厅重点科技创新团队计划项目(2013KCT-08);陕西省科技厅自然科学基础研究计划项目 ()

陕西科技大学学报(自然科学版)

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2096-398X

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