中南民族大学学报（自然科学版）Issue(3)：15-21,7.
新型1，2，4-三唑重金属离子荧光淬灭剂的合成、表征与性能
Synthesis, Characterization and Properties of Novel 1, 2, 4-Triazole Heavy Metal Ion Fluorescence Quencher
摘要
Abstract
To find out a novel fluorescent quencher that may rapidly detect and remove heavy metal ions , a series of heavy metal (Co, Cr, Mn, Ni) complexes with 4-amino-3,5-bis (o-hydroxyphenyl)-1, 2, 4-triazole as ligand were synthesized. Their structures and coordination modes were confirmed by IR , 1 H NMR, 13 C NMR, MS and element analysis .The TGA, ultraviolet spectra and fluorescence quenching properties were also discussed .The results showed these complexes had good thermal stability .The Mn and Ni complexes were decomposed into stable oxide at high temperatures .The UV absorption intensity of the complexes was weaker than that of the ligand .The fluorescence of ligand was quenched when the ligand was coordinated with metal ions, which indicated heavy metal ions (Co, Cr, Mn, Ni) are good fluorescence quenchers for 1, 2, 4-triazole ligand and could be removed as precipitate .关键词
1, 2, 4-三唑/金属配合物/合成/热性能/荧光淬灭剂Key words
1, 2, 4-triazole/metal complexes/synthesis/thermal performance/fluorescence quencher分类
化学化工引用本文复制引用
陈连清,谢林波,钟柔潮,兰少花,雷小萍,陆俭洁..新型1，2，4-三唑重金属离子荧光淬灭剂的合成、表征与性能[J].中南民族大学学报（自然科学版）,2015,(3):15-21,7.基金项目
国家自然科学基金资助项目（20702064，21177161）；人事部留学人员科技活动择优资助项目（BZY13007）；湖北省杰出青年基金资助项目（2013CFA034）；武汉市青年科技晨光计划（201271031422）；湖北省高等学校省级教学研究项目（JYS11001）；中南民族大学实验室开放与技改项目 （）
