石油化工2015，Vol.44Issue(12)：1421-1432,12.
均相催化O2氧化醇的研究进展(下)
Advances in Homogeneous Catalytic Oxidation of Alcohols by Molecular Oxygen
摘要
Abstract
Advances in the selective alcohol oxidation with molecular oxygen catalyzed by homogeneous catalyst systems,namely homogeneous transition metal(Cu,Fe,Co,V,Ru,Pd, Au) catalytic systems,non-metal catalytic system(2,2,6,6-tetramethyl-piperidy-1-oxy) and small organic molecule catalytic systems(2,3-dichloro-5,6- dicyano-1,4-benzoquinone),to aldehydes or ketones were reviewed. The application,advantages and disadvantages of the catalytic systems were discussed. The possible catalytic mechanisms of the main catalytic systems were focused on. Based on the existing researches,the development trends in this fi eld were also forecasted.关键词
分子氧/醇/选择氧化/均相催化Key words
molecular oxygen/alcohol/selective oxidation/homogeneous catalysis分类
化学化工引用本文复制引用
王连月,高爽..均相催化O2氧化醇的研究进展(下)[J].石油化工,2015,44(12):1421-1432,12.基金项目
国家自然科学基金资助项目(21403219). （21403219）
