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氮对金刚石缺陷发光的影响∗

张秀芝 王凯悦 李志宏 朱玉梅 田玉明 柴跃生

物理学报Issue(24):247802-0-247802-5,6.
物理学报Issue(24):247802-0-247802-5,6.DOI:10.7498/aps.64.247802

氮对金刚石缺陷发光的影响∗

Effect of nitrogen on the defect luminescence in diamond

张秀芝 1王凯悦 1李志宏 2朱玉梅 2田玉明 1柴跃生1

作者信息

  • 1. 太原科技大学材料科学与工程学院,太原 030024
  • 2. 天津大学材料科学与工程学院,天津 300072
  • 折叠

摘要

Abstract

The defect luminescences of types IIa, Ib and Ia diamond are investigated by the low-temperature micro-photoluminescence microspectroscopy. The results show that with the increase of nitrogen content, the interstitials and vacancies are trapped by the nitrogen atoms, then the luminescences of intrinsic defects such as GR1, 533.5 nm and 580 nm centers are weakened, while the emissions of nitrogen-related such as NV and 523.7 nm centers are strengthened. After high temperature annealing, the interstitials and vacancies in diamond become movable. The NV0 center is found in the IIa diamond, and the type Ib diamond presents the only strong NV luminescence. The H3 and N3 centers are observed due to the aggregation of nitrogen in Ia diamond. In addition, the nitrogen benefits the formations of the negative defects (3H center, NV− center) as the donor atom.

关键词

金刚石//缺陷/光致发光

Key words

diamond/nitrogen/defect/photoluminescence

引用本文复制引用

张秀芝,王凯悦,李志宏,朱玉梅,田玉明,柴跃生..氮对金刚石缺陷发光的影响∗[J].物理学报,2015,(24):247802-0-247802-5,6.

基金项目

国家留学基金委(批准号:2010625044)资助的课题.* Project partly supported by China Scholarship Council (Grant No.2010625044) (批准号:2010625044)

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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