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SrWO4∶Gd3+,Tb3+荧光粉的发光性质及能量传递∗

霍涌前 杨庆萍 孙涛 李甜甜 石蕾 张瑾 陈晓利 刘晓利

合成材料老化与应用Issue(6):69-74,104,7.
合成材料老化与应用Issue(6):69-74,104,7.

SrWO4∶Gd3+,Tb3+荧光粉的发光性质及能量传递∗

Luminescence Properties and Energy Transfer of SrWO4∶Gd3+,Tb3+

霍涌前 1杨庆萍 1孙涛 1李甜甜 1石蕾 1张瑾 1陈晓利 1刘晓利1

作者信息

  • 1. 延安大学化学与化工学院,陕西延安716000
  • 折叠

摘要

Abstract

One serie SrWO4∶Gd3+,Tb3+ fluorescent powder were synthesized in this paper. The structure,mor-phology and luminescence properties of the samples were characterized by XRD,SEM and luminescence spectrosco-py. XRD analysis confirmed the samples exhibited a body-centered tetragonal crystal structure. The particles of as-synthesized phosphors are basically spherical in shape,and well dispersed with the mean particle size of 3μm. In the emission spectrum of Sr0. 9 WO4∶0. 05Gd3+,0. 05Tb3+ excited by 223nm, the main peak is located at about 549nm due to the transition of 5 D4→7 F5 of Tb3+ emission. The PL intensity of Tb3+ in Sr0. 9 WO4∶0. 05Gd3+, 0. 05Tb3+ increases with the increase of x values due to an energy migration process like Gd3+→Tb3+occurred in the phosphors.

关键词

钨酸锶/发光性能/铽掺杂/荧光粉/稀土

Key words

SrWO4/luminescent properties/terbium doping/phosphor/rare earths

分类

数理科学

引用本文复制引用

霍涌前,杨庆萍,孙涛,李甜甜,石蕾,张瑾,陈晓利,刘晓利..SrWO4∶Gd3+,Tb3+荧光粉的发光性质及能量传递∗[J].合成材料老化与应用,2015,(6):69-74,104,7.

基金项目

国家自然科学基金(21101133)资助 (21101133)

合成材料老化与应用

OACSTPCD

1671-5381

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