化工进展Issue(1):57-64,8.DOI:10.16085/j.issn.1000-6613.2016.01.008
天然气水合物形成与生长影响因素综述
Review of influence factors of natural gas hydrate formation and growth
摘要
Abstract
Natural gas hydrate is a kind of complex clathrate crystal formed by water and natural gas molecules,which has an important significance for research and utilization in industries of oil/gas pipeline transportation,natural gas storage and refrigeration. While the formation and growth of natural gas hydrate is a complex process involving multi-components and multistages,and the influence of different factors on hydrate formation and growth still needs to be understood. This paper introduces the physical process of natural gas formation and three hypotheses of natural gas nucleation. Then,the influences of substrate amphipathy,additives,porous media environment and impurities,liquid composition,temperature,pressure and flow conditions on hydrate formation and growth are discussed. At last,this paper points out that quantification of inhibition of hydrate caused by different crude oil compositions,influence of wax on mass transfer and heat transfer during hydrate growth,and a microscopic mechanism of kinetic hydrate inhibition should be further studied in the future.关键词
天然气水合物/物理过程/形成/生长/影响因素Key words
natural gas hydrate/physical process/formation/growth/influence factor分类
能源科技引用本文复制引用
丁麟,史博会,吕晓方,柳扬,宫敬..天然气水合物形成与生长影响因素综述[J].化工进展,2016,(1):57-64,8.基金项目
国家自然科学基金(51274218,51306208,51134006)、国家科技重大专项(2011ZX05026-004)、中国石油大学(北京)科学基金(2462013YXBS010)及中国石油大学(北京)科研基金(2462014YJRC006)项目。 ()