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手性金属有机骨架材料的合成及其在对映异构体选择性分离中的应用

祁晓月 李先江 白玉 刘虎威

色谱Issue(1):10-15,6.
色谱Issue(1):10-15,6.DOI:10.3724/SP.J.1123.2015.10005

手性金属有机骨架材料的合成及其在对映异构体选择性分离中的应用

Synthesis and applications of chiral metal-organic framework in the selective separation of enantiomers

祁晓月 1李先江 1白玉 1刘虎威1

作者信息

  • 1. 北京大学化学与分子工程学院,北京 100871
  • 折叠

摘要

Abstract

Chirality is a universal phenomenon in nature. Chiral separation is vitally important in drug development,agricultural chemistry,pharmacology,environmental science,biology and many other fields. Chiral metal-organic frameworks( MOFs ) are a new group of porous materials with special topology and designable pore structures,as well as their high specific surface area,porosity,excellent thermal stability,solvent resistance,etc. Thus,chiral MOFs are promising with various applications in the field of analytical chemistry. This review summa-rizes the synthesis strategies of chiral MOFs and their applications in the selective separation of enantiomers,as well as related mechanism.

关键词

金属有机骨架化合物/手性分离/对映异构体/选择性萃取/综述

Key words

metal-organic frameworks/chiral separation/enantiomer/selective extraction/review

分类

化学化工

引用本文复制引用

祁晓月,李先江,白玉,刘虎威..手性金属有机骨架材料的合成及其在对映异构体选择性分离中的应用[J].色谱,2016,(1):10-15,6.

基金项目

国家自然科学基金项目(21175008);国家重大科学仪器设备开发专项项目(2013YQ510391).@@@@National Natural Science Foundation of China( Grant No.21175008);Research Equipment and Facilities Construction Program of the Ministry of Science and Technology of China( Grant No.2013YQ510391). ()

色谱

OA北大核心CSCDCSTPCDMEDLINE

1000-8713

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