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生物质对高灰熔点煤灰熔融特性的调控机制

徐美玲 李风海 李振珠

化学工程Issue(1):69-74,6.
化学工程Issue(1):69-74,6.DOI:10.3969/j.issn.1005-9954.2016.01.015

生物质对高灰熔点煤灰熔融特性的调控机制

Regulatory mechanism of biomass on the ash fusion characteristics of the coal with a high fusion temperature

徐美玲 1李风海 1李振珠2

作者信息

  • 1. 菏泽学院 化学化工系,山东 菏泽 274000
  • 2. 山东洪业化工集团股份有限公司,山东 东明 274500
  • 折叠

摘要

Abstract

To explore the effects of biomass on the ash fusion temperatures (AFTs)of the coal with a high melting point,the mixtures′AFTs of Hebi coal and Jincheng anthracite added with peanut and corn straw in different mass ratios were studied.The AFTs′variations of mixtures were examined on an intelligent ash-melting point measuring device,and their mechanism was analyzed by X-Ray Fluorescence Spectrometer (XRF),and X-ray diffraction (XRD).The results show that the AFTs of the mixtures decrease slowly with the increase of biomass ratios. Choosing the appropriate proportion can make the ash flow temperature (FT)meet the demand of liquid slag discharge.The minerals with a high melting point in the mixture ashes can react with other ash compositions,which lead to the formation of fayalite,hercynite,leucite,anorthite and microcline,etc.These minerals can form the low-temperature eutectic,leading to the decrease of ash fusion temperatures.

关键词

生物质/高灰熔点煤/灰熔融特性/矿物质演变

Key words

biomass/high melting point coal/ash fusion characteristics/mineral evolution

分类

化学化工

引用本文复制引用

徐美玲,李风海,李振珠..生物质对高灰熔点煤灰熔融特性的调控机制[J].化学工程,2016,(1):69-74,6.

基金项目

中国科学院战略性先导科技专项(XDA07050103);山东省自然科学基金(ZR2014BM014);煤炭转化国家重点实验室开放基金 ()

化学工程

OA北大核心CSCDCSTPCD

1005-9954

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