杭州师范大学学报（自然科学版）Issue(1)：1-6,6.DOI:10.3969/j.issn.1674-232X.2016.01.001
两个含2-（1 H-苯并咪唑基）-4-溴苯酚的钴（Π）、锌（Π）配合物的合成、晶体结构及表征
Synthesis,Crystal Structure and Properties of Co (Ⅱ),Zn(Ⅱ) Complexes with 2-(1 H-benzimidazol-2-yl)-4-bromophenolato
范艳 1瞿志荣1
作者信息
- 1. 杭州师范大学有机硅化学及材料技术教育部重点实验室，浙江 杭州311121
- 折叠
摘要
Abstract
Thecomplex1[Co(C13H8BrN2O)2]・2(CH3OH)wereself‐assembledwithCo(CH3COO)2 ・4H2Oandthe 2‐(1 H‐benzimidazol‐2‐yl)‐4‐bromophenolato as raw material by a hydrothermal method and the same ligands with Zn(CH3COO)2 ・2H2O by natural evaporation method self‐assemble into complex 2 [Zn(C13 H8BrN2O)2 ]・DMF・3H2O . And the crystal structure of the complexes was characterized by X‐ray crystal diffraction . The results show that the complexes 1 and 2 crystallize in triclinic , space group Pī. Complex 1 assembles into a 1D chain structure by the intermolecular hydrogen bonding interactions and the complex 2 assembles into a 2D layer structure . The fluorescent property and thermal stability are also studied ,the results show that complex 2 with stronger fluorescence intensity than complex 1 .关键词
2-(1H-苯并咪唑基)-4-溴苯酚/配合物/晶体结构/荧光Key words
2-(1 H-benzimidazol-2-yl)-4-bromophenolato/complex/crystal structure/fluorescent分类
化学化工引用本文复制引用
范艳,瞿志荣..两个含2-（1 H-苯并咪唑基）-4-溴苯酚的钴（Π）、锌（Π）配合物的合成、晶体结构及表征[J].杭州师范大学学报（自然科学版）,2016,(1):1-6,6.
