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秸秆乙醇残渣三聚氰胺脲醛树脂的制备与固化性能研究

高士帅 胡岚方 南静娅 赵临五 王春鹏 储富祥

生物质化学工程Issue(1):1-5,5.
生物质化学工程Issue(1):1-5,5.DOI:10.3969/j.issn.1673-5854.2016.01.001

秸秆乙醇残渣三聚氰胺脲醛树脂的制备与固化性能研究

P reparation and Curing P erformance of Straw Ethanol Residue-melamine-urea-formaldehyde Resin

高士帅 1胡岚方 1南静娅 1赵临五 1王春鹏 1储富祥2

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所 生物质化学利用国家工程实验室 国家林业局 林产化学工程重点开放性实验室 江苏省 生物质能源与材料重点实验室,江苏 南京210042
  • 2. 中国林业科学研究院林业新技术研究所,北京100091
  • 折叠

摘要

Abstract

The straw ethanol residue-melamine-urea-formaldehyde ( ERMUF ) resin was prepared with straw ethanol residue (ER), melamine(M), urea(U) and formaldehyde(F). The effects of the contents of ER, M and U on the performance of ERMUF resin and the three-plyboard were studied. The optimal raw material ratios were n( F)/n( U) 1.5, n( M)/n( F) 0.15 and m(ER)/m(ER+U) 0.48. The formaldehyde emission from three-plyboards prepared with the ERMUF resin obtained under these above ratios was 0.24 mg/L and met E0 grade. The bonding strength was 1.03 MPa and met the requirement of typeⅡplyboard. The curing behavior of ERMUF resins with different curing agents was also investigated. The results showed that the combination of NH4Cl and H3PO4 gave good curing performance and the suitable dosages of additions were 1% NH4Cl and 0.5%H3PO4. The corresponding curing time of ERMUF resin was short (148s), the bonding strength of three-plyboard was srtong(1.09MPa) and the formaldehyde emission was 0.25 mg/L.

关键词

秸秆乙醇残渣/脲醛树脂/固化性能

Key words

straw ethanol residue/urea-formaldehyde resin/curing behavior

分类

化学化工

引用本文复制引用

高士帅,胡岚方,南静娅,赵临五,王春鹏,储富祥..秸秆乙醇残渣三聚氰胺脲醛树脂的制备与固化性能研究[J].生物质化学工程,2016,(1):1-5,5.

基金项目

林业公益性行业科研专项(201304606) (201304606)

生物质化学工程

OA北大核心

1673-5854

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