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超支化季铵盐表面活性剂的合成及其在碱减量中的应用

田森 李佩容 胡慧成 周向东

印染助剂Issue(2):12-16,5.
印染助剂Issue(2):12-16,5.

超支化季铵盐表面活性剂的合成及其在碱减量中的应用

Synthesis of quaternary ammonium salt surfactant and its application in the alkali decrement

田森 1李佩容 2胡慧成 1周向东2

作者信息

  • 1. 苏州大学纺织与服装学院,江苏苏州 215021
  • 2. 苏州大学现代丝绸国家工程实验室,江苏苏州 215123
  • 折叠

摘要

Abstract

Epichlorohydrin was grafted onto the hyperbranched polyester Boltorn H20, and the intermedi⁃ate was gained, then, the intermediate was modified by hexadecyldimethylamine, at last the hyperbranched quaternary ammonium salt surfactant H20Cl6N was prepared. The surface activity of H20Cl6N was character⁃ized and the results stated that its critical micel e concentration was 1.250 g/L, minimum interfacial tension was 33.720 mN/m, and toluene solubilization capacity was 0.32 mL/g. The deweighting loss percentage and rupture strength of polyester fabric were 31% and 540 N, respectively, when H20Cl6N was accelerator for al⁃kali decrement. The deweighting loss percentage and rupture strength of polyester fabric were 32% and 526 N, respectively, when 1227 was accelerator for alkali decrement. Thus, H20Cl6N made less damage to the polyester fabric strength, when there was a similar deweighting loss percentage between H20Cl6N and 1227.

关键词

超支化季铵盐/表面活性剂/碱减量

Key words

hyperbranched quaternary ammonium salt/surfactant/alkali decrement

分类

化学化工

引用本文复制引用

田森,李佩容,胡慧成,周向东..超支化季铵盐表面活性剂的合成及其在碱减量中的应用[J].印染助剂,2016,(2):12-16,5.

基金项目

江苏高校优势学科建设工程资助项目 ()

印染助剂

OA北大核心CSTPCD

1004-0439

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