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Fe(OH)3胶体对铀的吸附行为

熊骁 王清良 李乾 胡鄂明 冯志钢 李中 王星星

原子能科学技术Issue(1):39-45,7.
原子能科学技术Issue(1):39-45,7.DOI:10.7538/yzk.2016.50.01.0039

Fe(OH)3胶体对铀的吸附行为

Adsorption Behavior of Uranium on Fe (OH)3 Colloid

熊骁 1王清良 1李乾 1胡鄂明 1冯志钢 1李中 1王星星1

作者信息

  • 1. 南华大学 核资源工程学院,湖南 衡阳 421001
  • 折叠

摘要

Abstract

In order to study the adsorption of uranium on Fe(OH)3 colloid in situ leac‐hing of uranium ,the Fe(OH)3 colloid was prepared in absolute ethanol ,and the adsorp‐tion performance of uranium on Fe(OH)3 colloid was detected .The effects of pH value , initial uranium concentration ,and the contact time were analyzed .As for the adsorption dynamics ,the pseudo‐first‐order ,composite‐second‐order and Elovich dynamic models were comparatively calculated and discussed .The results show that the Elovich dynamic model is fit to describe the adsorption of uranium on Fe (OH )3 colloids .As for the adsorption thermodynamics ,the Freundlich and Langmuir adsorption isotherm models were applied to analyze and fit the experimental equilibrium data .It is found that the equilibrium data agree well with the Freundlich model .In conclusion ,the adsorption of uranium on Fe(OH)3 colloid belongs to the single layer physical adsorption of uneven surface .The laser particle size and SEM analysis results reveal that the Fe (OH )3 colloids show a good adsorption performance ,and the surface adsorption takes preced‐ence in the adsorption process .

关键词

Fe(OH)3胶体//吸附/动力学/等温线

Key words

Fe(OH)3 colloid/uranium/adsorption/kinetics/isotherm

分类

矿业与冶金

引用本文复制引用

熊骁,王清良,李乾,胡鄂明,冯志钢,李中,王星星..Fe(OH)3胶体对铀的吸附行为[J].原子能科学技术,2016,(1):39-45,7.

基金项目

国家自然科学基金资助项目 ()

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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