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新型三角形电极圆环离子阱的理论模拟研究

杨海洋 许崇晟 岳磊 Mikhail Sudakov 潘远江 丁传凡

分析化学Issue(3):482-488,7.
分析化学Issue(3):482-488,7.DOI:10.11895/j.issn.0253-3820.150900

新型三角形电极圆环离子阱的理论模拟研究

Optimization of Performance of Toroidal Ion Trap with Triangular Electrode by Theoretical Simulation

杨海洋 1许崇晟 1岳磊 2Mikhail Sudakov 1潘远江 2丁传凡1

作者信息

  • 1. 复旦大学化学系,上海市分子催化与功能材料重点实验室,上海200433
  • 2. 浙江大学化学系,杭州310027
  • 折叠

摘要

Abstract

The toroidal ion trap is an ideal candidate for miniaturized ion trap because it has much higher ion trapping capacity than a standard quadrupole ion trap of equal trapping dimensions. A novel toroidal ion trap mass analyzer with triangular electrode which contained a filament end cap, a detector endcap, an inner ring and an outer ring was reported. After designing and optimizing the electrodes by theoretical simulations, we found that the asymmetric triangle electrodes could reduce the affection from toroidal shape and improve the ion ejection rate and the mass resolution of the ion trap. The best design of the toroidal ion trap with a mass resolution of 1486 at m/z 609 was obtained.

关键词

圆环离子阱/理论模拟/不对称电极/质量分辨/多级场分析

Key words

Toroidal ion trap/Theoretical simulation/Asymmetric electrodes/Mass resolution/High-order multipoles analysis

引用本文复制引用

杨海洋,许崇晟,岳磊,Mikhail Sudakov,潘远江,丁传凡..新型三角形电极圆环离子阱的理论模拟研究[J].分析化学,2016,(3):482-488,7.

分析化学

OA北大核心CSCDCSTPCD

0253-3820

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