化工进展Issue(2)：364-368,5.DOI:10.16085/j.issn.1000-6613.2016.02.004
茂钛配合物水解的研究手段
Methods to study titanium complexes hydrolysis
李淑云 1冯书晓 1章亚东1
作者信息
- 1. 郑州大学化工与能源学院，河南郑州 450001
- 折叠
摘要
Abstract
The hydrolysis of titanium complexes has seriously limited their applications. Their hydrolytic characteristic was closely related to the antitumor activity. Therefore,it was necessary to use proper testing methods to evaluate the hydrolytic behavior of titanium complexes. This article introduced a series of methods for investigating the hydrolysis of titanium complexes,including UV-Vis,1H NMR,X-ray crystallography,potentiometric analysis,conductivity method,and quantum chemistry computations. The strength and shortcomings of those methods were analyzed and compared. It was also described that the methods contributed to the investigations on the hydrolytic kinetic of titanium complexes,which could promote the progress of titanium complexes on medical and chemical industry.关键词
配合物/水解/紫外-可见分光光度测定法/核磁共振/X射线晶体学/电化学/电解/计算化学Key words
complexes/hydrolysis/UV-Vis/nuclear magnetic resonance (NMR)/X-ray crystallography/electrochemistry/electrolysis/computational chemistry分类
化学化工引用本文复制引用
李淑云,冯书晓,章亚东..茂钛配合物水解的研究手段[J].化工进展,2016,(2):364-368,5.
