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反应路径和颗粒吸热对气化炉数值模拟的影响

钟汉斌 蓝兴英 高金森

化工进展Issue(2):376-382,7.
化工进展Issue(2):376-382,7.DOI:10.16085/j.issn.1000-6613.2016.02.006

反应路径和颗粒吸热对气化炉数值模拟的影响

Effects of reaction pathway and particle heat absorption on gasifier:a numerical study

钟汉斌 1蓝兴英 2高金森2

作者信息

  • 1. 西安石油大学化学化工学院,陕西西安 710065
  • 2. 中国石油大学 北京 重质油国家重点实验室,北京102249
  • 折叠

摘要

Abstract

The gasification technology is an efficient way to process inferior crude oil,unconventional oil and coal with lower emissions,and numerical simuation is an important method to reveal the complex flow and reaction behavior in the gasifier. In order to evaluate the influence of volatile reaction pathway and particle reaction heat absorption ratio,the Orimulsion gasification process in an entrained-flow gasifier was simulated with Eulerian-Lagrangian method. The homogenous reactions and heterogeneous reactions were described by the finite-rate/eddy-dissipation model and particle surface reaction model,respectively. The simulation results demonstrate that the reaction pathway of volatile mainly affects temperature and species distributions in the near-nozzle region,while those at the outlet of the gasifier change only slightly. However,the effect of particle heat absorption ratio is almost negligible due to the lower amount of fixed carbon in the Orimulsion and the small reaction heat of coke combustion.

关键词

气化/数值模拟/反应历程/吸热/奥里乳化油

Key words

gasification/numerical study/reaction pathway/heat absorption/orimulsion

分类

化学化工

引用本文复制引用

钟汉斌,蓝兴英,高金森..反应路径和颗粒吸热对气化炉数值模拟的影响[J].化工进展,2016,(2):376-382,7.

基金项目

国家重点基础研究发展计划项目(2012CB215003)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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