化工进展Issue(2)：445-452,8.DOI:10.16085/j.issn.1000-6613.2016.02.016
锌空气电池锌负极研究进展
Research status of zinc anode for zinc-air batteries
摘要
Abstract
In renewable energy power generation and electric vehicle technology,the development of high energy density,safe,reliable and pollution-free zinc-air batteries is of important social and economic value. However,some problems of zinc anode has seriously hindered its application. Therefore,this paper systematically reviews the progress on corrosion,dendrite formation,shape change and passivation of zinc anode. The inhibition effects of inorganic corrosion inhibitors,organic corrosion inhibitors and mixed corrosion inhibitors on hydrogen evolution are introduced,and the effects of additives,separators and operating conditions on the formation and growth of dendrite are discussed. The mechanism of shape change and the common solutions are reviewed,and the causes of passivation and its effects are described briefly. The analysis shows that the electrically rechargeable zinc-air batteries have more market prospects than the primary ones. Also,the inhibition of hydrogen corrosion is still the focus toward zinc anode studies in the future,and improving the capacity and power stability during cycling is the key to the practical application.关键词
锌负极/析氢腐蚀/枝晶生长/电极形变/钝化Key words
zinc anode/corrosion/dendrite formation/shape change/passivation分类
信息技术与安全科学引用本文复制引用
洪为臣,雷青,马洪运,王保国..锌空气电池锌负极研究进展[J].化工进展,2016,(2):445-452,8.基金项目
国家自然科学基金（21276134）及国家863计划（2012AA051203）项目。 （）
