化工进展Issue(2)：524-527,4.DOI:10.16085/j.issn.1000-6613.2016.02.027
常压条件下Pd/C催化邻氯硝基苯加氢反应
Hydrogenation performance ofo-chloronitrobenzene over Pd/C under atmospheric pressure
摘要
Abstract
Activated carbon supported noble metal Pd,Pt and Ru catalysts were prepared by chemical reduction method,and were used in the synthesis ofo-chloroaniline fromo-chloronitrobenzene without any dechlorinating inhibitor and promoter added. The results of the experiments demonstrated that the Pd/C catalysts had better catalytic performances than Pt/C catalysts and Ru/C catalysts. The effects of solvent,reaction temperature,reaction time and other factors were examined using a Pd/C catalyst. The results showed that a 100% conversion ofo-chloronitrobenzene was achieved with a selectivity of 87.4% too-chloroaniline by small amount of 5% Pd/C catalyst under atmospheric pressure. Furthermore,the catalyst could be reused for 6 runs without significant loss of catalytic activity. The new technology was featured as lower reaction pressure,lower catalyst dosage,shorter reaction time and lower dechlorinating,and therefore suitable for industrial production.关键词
钯/活性炭/邻氯硝基苯/邻氯苯胺/催化/加氢Key words
palladium/activated carbon/o-chloronitrobenzene/o-chloroaniline/catalysis/hydrogenation分类
化学化工引用本文复制引用
刘贤响,杨拥军,尹笃林,雷涤尘,杨静,苏胜培..常压条件下Pd/C催化邻氯硝基苯加氢反应[J].化工进展,2016,(2):524-527,4.基金项目
湖南省教育厅科研项目（13C562，15B134）。 （）
