化工进展Issue(2)：586-594,9.DOI:10.16085/j.issn.1000-6613.2016.02.039
金属有机骨架材料吸附去除环境污染物的进展
Progress in the applications of metal-organic frameworks in adsorption removal of hazardous materials
摘要
Abstract
Due to the high specific surface area,high/tunable porosity,controllable structure,open metal sites and the possibility to functionalize,metal organic frameworks (MOFs) as promising adsorption materials have attracted considerable attention in recent decade. This critical review focuses on the progress in the applications of MOFs in adsorption removal of organic pollutants/heavy metal ion from wastewater and sulfur-containing compounds (SCCs)/nitrogen-containing compounds (NCCs) from fuel. The adsorption properties of MOFs for different hazardous materials and adsorption mechanism were discussed. It was demonstrated that the porosity,pore size and the central metal ions was important for the adsorption,which was found to proceed through a number of different mechanisms such as electrostatic interactions,π-π stacking/interactions,acid-base interactions and hydrogen bonding. The adsorption properties can be promoted by the functional modification of MOFs. The research trend in the future was also prospected.关键词
金属有机骨架材料/环境污染物/吸附Key words
metal-organic frameworks/hazardous materials/adsorption分类
通用工业技术引用本文复制引用
李小娟,何长发,黄斌,林振宇,刘以凡,林春香..金属有机骨架材料吸附去除环境污染物的进展[J].化工进展,2016,(2):586-594,9.基金项目
国家自然科学基金（21407026）、福建省杰出青年科学基金（2014J06005）及福州大学能源与环境光催化国家重点实验室自主课题基金（2014B02）项目。 （）
