化工学报Issue(2)：379-389,11.DOI:10.11949/j.issn.0438-1157.20151172
水盐体系相平衡研究进展
Progress in study on phase equilibria of salt-water systems
摘要
Abstract
The phase equilibria and phase diagrams of salt-water systems constitute the theoretical basis for chemical industry of inorganic salts. The fundamental studies on the phase equilibrium can provide firm support for the comprehensive development and utilization of salt lake salt resources. In this paper, the recent domestic and international research advances and methods on phase equilibria of slat-water systems from both experimental and theoretical perspectives are summarized. In particular, the experimental methods on the determination of phase diagrams for stable and metastable phase equilibrium systems as well as the factors which cause the change of phase interval and solid crystal type are presented. In addition, based on the up-to-date theoretical methods including thermodynamic models, statistical mechanics theories and computer simulations, the outline of their principles, current situations and possible extensions toward the investigation of stable and metastable phase equilibrium systems are introduced. Finally, the research hotspots in this domain are discussed along with the expectations on the future development.关键词
水盐体系/相平衡/相图/盐湖资源Key words
salt-water system/phase equilibria/phase diagrams/salt lakes resources分类
化学化工引用本文复制引用
张杰,史学伟,赵双良,宋兴福,于建国..水盐体系相平衡研究进展[J].化工学报,2016,(2):379-389,11.基金项目
国家高技术研究发展计划项目（2011AA06A107）；化学工程联合国家重点实验室开放课题项目（SKL-ChE-13C04）；上海青年科技启明星计划A类项目（14QA140300）。@@@@supported by the National High Technology Research and Development Program of China (2011AA06A107), the Open Project of State Key Laboratory of Chemical Engineering of China (SKL-ChE-13C04) and the Shanghai Science and Technology Committee Rising-Star Program (14QA14031300) （2011AA06A107）
