物理化学学报Issue(2)：399-404,6.DOI:10.3866/PKU.WHXB201511272
固态Photo-CIDNP效应
The Solid-State Photo-CIDNP Effect
摘要
Abstract
Photochemical y induced dynamic nuclear polarization (photo-CIDNP) is an effect that produces non-Boltzmann nuclear spin polarization, which can be observed as a modification of signal intensity in nuclear magnetic resonance (NMR) spectroscopy. The effect is wel known in liquid-state NMR, where it is explained most general y by the classical radical pair mechanism (RPM). In the solid-state, additional mechanisms are operative in the spin-dynamics of radical pairs, such as three-spin mixing (TSM), differential decay (DD) and differential relaxation (DR). The observed solid-state photo-CIDNP effect is strongly magnetic field dependent, and this field-dependence is wel distinguished for the various nuclei. Here, we provide an account of the phenomenology, theory and properties of the magnetic field dependence of the solid-state photo-CIDNP effect.关键词
光化学诱导动态核极化/魔角旋转/核磁共振/自由基对/自旋化学Key words
Photo-CIDNP/Magic angle spinning/Nuclear magnetic resonance/Radical pair/Spin chemistry分类
化学化工引用本文复制引用
王孝杰,THAMARATH Smitha Surendran,ALIA A.,BODE Bela E.,MATYSIK Jörg..固态Photo-CIDNP效应[J].物理化学学报,2016,(2):399-404,6.基金项目
The project was supported by the Netherlands Organization for Scientific Research (NWO)(713.012.001).荷兰科学研究组织(NWO)(713.012.001)资助项目 （NWO）
