云南化工Issue(1)：24-27,4.DOI:10.3969/j.issn.1004-275X.2016.01.006
高沸点硫醇逆酯锡的合成
Study on Synthesis of High Boiling Point Revers Ester Mercaptid Methyltin
王丽媛 1蒋丽红 2王战蒙 1易强顺 1陈树 1胡艳华 1刘莉1
作者信息
- 1. 云南锡业股份化工材料分公司 云南 个旧 661000
- 2. 昆明理工大学化工学院 昆明 650500
- 折叠
摘要
Abstract
The synthesis conditions of revers ester mercaptid methyltin by using methyltin chlorine and mercaptoethyl oleate as raw materials was studied.The effects of raw material ratio,the pH of reaction process,the end pH of reaction and reaction temperature were investigated.It was found that the revers ester mercaptid methyltin yield of 97.65% was obtained when the reaction was performed in the weak acid envi-ronment at 15 ~20 ℃ with the ratio of methyltin chlorine and mercaptoethyl oleate 1∶1.1.The boiling point of revers ester mercaptid methyltin was about 340.2 ℃,which was higher by about 52 ℃ than that of tradi-tional mercaptid methyltin.关键词
硫醇逆酯锡/高沸点/甲基氯化物/十八烯酸酯Key words
revers ester mercaptid methyltin/high boiling point/methyltin chlorine/mercaptoethyl o-leate分类
化学化工引用本文复制引用
王丽媛,蒋丽红,王战蒙,易强顺,陈树,胡艳华,刘莉..高沸点硫醇逆酯锡的合成[J].云南化工,2016,(1):24-27,4.
