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掺铈PI/SnO2复合薄膜的制备及光催化性能

孙博华 李艳丽 李青

印染助剂2016,Vol.33Issue(3):8-12,5.
印染助剂2016,Vol.33Issue(3):8-12,5.

掺铈PI/SnO2复合薄膜的制备及光催化性能

Preparation and photocatalytic properties of PI/SnO2 films doping with cerium

孙博华 1李艳丽 1李青1

作者信息

  • 1. 北京服装学院材料科学与工程学院,北京 100029
  • 折叠

摘要

Abstract

The PI/SnO2 films doping with cerium were prepared on flexible polyimide (PI) substrate via di⁃rect ion exchange method. The effect of different preparation conditions on the photocatalytic properties of the composite films were studied. Furthermore, the effects of the doping amount of cerium ion and the con⁃centration of ion exchange liquid on photocatalytic performance were also studied. The films were character⁃ized by SEM, EDAX, XRD and FTIR. The photocatalytic performance of the films was evaluated by the degrada⁃tion rate of the methylene blue. The results showed that the PI/SnO2 composite films with 30% (mass frac⁃tion) cerium, 0.4 mol/L total ion exchange solution concentration and calcined at 330 ℃ for 4 h, had perfect photocatalytic performance. The methylene blue degradation rate reached 94.5% at 2 h and TOC removal rate was 75.3%. The films could be recycled and showed a good degradation performance.

关键词

聚酰亚胺/离子交换/金属氧化物/光催化

Key words

polyimide/ion exchange/metal ic oxide/photocatalysis

分类

化学化工

引用本文复制引用

孙博华,李艳丽,李青..掺铈PI/SnO2复合薄膜的制备及光催化性能[J].印染助剂,2016,33(3):8-12,5.

基金项目

国家自然科学基金(51273018);北京市教委科技面上项目(KM201310012006);北京服装学院研究生科研创新 ()

印染助剂

OA北大核心CSTPCD

1004-0439

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