中南民族大学学报（自然科学版）2016，Vol.35Issue(1)：1-6,6.
邻菲啰啉缩单胺类席夫碱衍生物及其铕配合物的合成和光物理性能研究
Synthesis and Photophysical Properties of Phenanthroline Monoamine Schiff Base Derivatives and Their Europium Complexes
摘要
Abstract
In order to change the ligand type of the rare earth europium complexes and develop materials of better red light emission, three novel europium complexes were synthesized with Eu(Ⅲ) as the central atom, acetylacetone ( acac) as the first ligand, and three phenanthroline monoamine schiff base derivatives as the respective second ligand. The complexes were tested with UV and fluorescence spectra and their photophysical properties were also discussed. The results showed that the absorption in the UV region was enhanced gradually with the increase of the conjugation degree of the second ligand. The fluorescence emission peak was at about 613 nm attributed to the 5 D0→7 F2 characteristic transition of Eu3+. All three complexes emitted bright red fluorescence under UV exposure.关键词
邻菲啰啉席夫碱衍生物/稀土铕配合物/红光材料/光物理性能Key words
phenanthroline schiff base derivatives/rare earth europium complexes/red light material/photophysical properties分类
化学工程引用本文复制引用
陈连清,周泉,黄林伟,谢林波..邻菲啰啉缩单胺类席夫碱衍生物及其铕配合物的合成和光物理性能研究[J].中南民族大学学报（自然科学版）,2016,35(1):1-6,6.基金项目
国家自然科学基金资助项目(20702064,21177161,31402137) （20702064,21177161,31402137）
人事部留学人员科技活动择优资助项目(BZY13007) （BZY13007）
湖北省杰出青年基金资助项目(2013CFA034) （2013CFA034）
湖北省青年英才开发计划(RCJH15001) （RCJH15001）
武汉市青年科技晨光计划(201271031422) （201271031422）
