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异丁烷-丁烯固体酸烷基化反应动力学研究进展

刘晓宇 周祥 郭锦标 王鑫磊 付翁

化工进展2016,Vol.35Issue(4):1007-1011,5.
化工进展2016,Vol.35Issue(4):1007-1011,5.DOI:10.16085/j.issn.1000-6613.2016.04.006

异丁烷-丁烯固体酸烷基化反应动力学研究进展

Advances in the research development of isobutane/butene solid acid-catalyzed alkylation kinetics

刘晓宇 1周祥 1郭锦标 1王鑫磊 1付翁1

作者信息

  • 1. 中国石油化工股份有限公司石油化工科学研究院,北京100083
  • 折叠

摘要

Abstract

Kinetic analysis for understanding the reaction mechanism and hydrocarbon transformations rules has both theoretical and practical significance. The typical development and main research methods at different scales for alkylation kinetics are reviewed in this paper. Recommendations for improving the catalyst are made. The molecular-based kinetic modeling could provide detailed and explicit descriptions of the intrinsic kinetic properties,which reflect the relationship between the kinetic parameters and the feedstock,reaction conditions and catalyst. Mechanistic kinetic modeling could show important theoretical support for the optimization of reactor configuration,technological process and catalysts research.

关键词

烷基化/固体酸/动力学/催化剂失活/机理层面动力学模型

Key words

alkylation/solid acid/kinetics/catalyst deactivation/mechanistic kinetic modeling

分类

能源科技

引用本文复制引用

刘晓宇,周祥,郭锦标,王鑫磊,付翁..异丁烷-丁烯固体酸烷基化反应动力学研究进展[J].化工进展,2016,35(4):1007-1011,5.

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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