杭州师范大学学报（自然科学版）2016，Vol.15Issue(2)：119-123,5.DOI:10.3969/j.issn.1674-232X.2016.02.002
羟基硅油的基质辅助激光解吸电离飞行时间质谱表征研究
Structural Characterization of Hydroxyl Silicone Oil by MALDI-TOF MS
摘要
Abstract
Oligomeric hydroxyl silicone oil was successfully characterized by matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry with pyridine‐modified 2 ,5‐dihydroxybenzoic acid as the matrix .The analysis of a serial of silicone oil samples by the MS spectra indicated that the polymers tended to be ionized by the attachment with Na+ and K+ , and the corresponding average molecular mass ,degree of polymerization ,polydispersity index and hydroxyl content were calculated .关键词
羟基硅油/基质辅助激光解析电离飞行时间质谱/2,5-二羟基苯甲酸/结构表征Key words
hydroxyl silicone oil/MALDI-TOF MS/2 ,5-dihydroxybenzoic acid/structural characterization分类
化学化工引用本文复制引用
方丽雯,陈萌萌,朱晓清,瞿志荣,蒋可志..羟基硅油的基质辅助激光解吸电离飞行时间质谱表征研究[J].杭州师范大学学报（自然科学版）,2016,15(2):119-123,5.基金项目
国家自然科学青年基金项目（21205025）；浙江省自然科学基金项目（LY15B050007）；浙江省分析测试项目（2016C37017）． （）
