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β-Bi 2 O3的制备及光催化性能研究

张冰冰 张大凤 蒲锡鹏 高美超 吕冬冬

聊城大学学报(自然科学版)2016,Vol.29Issue(1):33-36,46,5.
聊城大学学报(自然科学版)2016,Vol.29Issue(1):33-36,46,5.

β-Bi 2 O3的制备及光催化性能研究

Synthesis ofβ-Bi2 O3 and its VisibIe Light PhotocataIytic Performance

张冰冰 1张大凤 1蒲锡鹏 1高美超 1吕冬冬1

作者信息

  • 1. 聊城大学 材料科学与工程学院,山东 聊城 252059
  • 折叠

摘要

Abstract

β‐Bi2 O3 was synthesized by a precipitation method ,using cetyl‐trimethyl ammonium bro‐mide ,bismuth nitrate ,concentrated nitric acid and sodium hydroxide solution as raw materials .The as‐synthesized samples were characterized by X‐ray powder diffraction and ultraviolet‐visible spectropho‐tometer .The influence of temperature of NaOH solution on the formation of β‐Bi2O3 was systematically investigated .Moreover ,the influence of the addition of HCl on the visible light photocatalytic perform‐ance and corresponding intrinsic mechanism were studied .The experimental results show that the pureβ‐Bi2 O3 samples could be obtained when NaOH solution was heated to boiling (98℃) .The photoactivity of β‐Bi2 O3 was significantly improved ,due to the formation of BiOCl layer on the surface β‐Bi2 O3 ,which results in inhibited recombination of electrons and holes and thus improved photocatalytic performance .

关键词

β-Bi2O3/光催化/BiOCl/可见光

Key words

β-Bi2 O3/photocatalysis/BiOCl/visible-light

分类

化学化工

引用本文复制引用

张冰冰,张大凤,蒲锡鹏,高美超,吕冬冬..β-Bi 2 O3的制备及光催化性能研究[J].聊城大学学报(自然科学版),2016,29(1):33-36,46,5.

基金项目

国家自然科学基金项目(51172102);山东省高等学校科技计划项目(J15LA10)资助 ()

聊城大学学报(自然科学版)

OACHSSCD

1672-6634

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