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PLA/PBAT/PLA-g-MAH可生物降解复合材料的形态结构与性能分析

周志斌 刘跃军 谭海英

包装学报2016,Vol.8Issue(2):8-14,7.
包装学报2016,Vol.8Issue(2):8-14,7.DOI:10.3969/j.issn.1674-7100.2016.02.002

PLA/PBAT/PLA-g-MAH可生物降解复合材料的形态结构与性能分析

Morphological Structure and Properties of PLA/PBAT/PLA-g-MAH Biodegradable Composites

周志斌 1刘跃军 1谭海英1

作者信息

  • 1. 湖南工业大学 包装与材料工程学院,包装新材料与技术重点实验室,湖南 株洲 412007
  • 折叠

摘要

Abstract

Poly(lactic acid)-graft-maleic anhydride (PLA-g-MAH) prepared by melt blending was used to compatiblize poly(lactic acid)/poly(butylene adipate-co-butylene terephthalate) (PLA/PBAT) blends. The structure and properties of PLA/PBAT/PLA-g-MAH composites were investigated by fourier transform infrared spectroscopy (FTIR), scanning elec-tron microscope (SEM), universal testing machine, pendulum impact tester, differential scanning calorimeter (DSC) and the hydrolysis of alkaline solution. SEM results showed that the phase interface became blurry between PLA and PBAT in PLA/PBAT blends with compatibilizer PLA-g-MAH, indicated that the PLA-g-MAH had certain compatibilized effect on PLA/PBAT blends. The incorporation of PLA-g-MAH resulted in a slight decrease of tensile strength and flexural strength compared with pure PLA, but improved impact strength and elongation at break about 17 times compared with pure PLA with added PLA-g-MAH. Moreover, the adding of PLA-g-MAH improved the biodegradability of PLA/PBAT blend.

关键词

马来酸酐接枝聚乳酸/聚己二酸-对苯二甲酸丁二醇酯/力学性能/生物降解性能

Key words

poly(lactic acid)-graft-maleic anhydride/poly(butylene adipate-co-butylene terephthalate)/mechanical properties/biodegradability

分类

通用工业技术

引用本文复制引用

周志斌,刘跃军,谭海英..PLA/PBAT/PLA-g-MAH可生物降解复合材料的形态结构与性能分析[J].包装学报,2016,8(2):8-14,7.

基金项目

国家自然科学基金资助项目(11372108),湖南省自然科学基金资助项目(14JJ5021),湖南省高校创新平台开放基金资助项目 ()

包装学报

1674-7100

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