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去除猪场沼液重金属 Pb(II)的离子印迹膜制备及其应用

肖艳春 黄婧 林香信 陈彪

福建农业学报2016,Vol.31Issue(1):57-62,6.
福建农业学报2016,Vol.31Issue(1):57-62,6.

去除猪场沼液重金属 Pb(II)的离子印迹膜制备及其应用

Preparation and Application of Ion-imprinted Membrane for Pb (II)Removal from Pig Farm Biogas Slurry

肖艳春 1黄婧 1林香信 2陈彪1

作者信息

  • 1. 福建省农业科学院农业技术工程研究所,福建 福州 350003
  • 2. 福建省农业科学院农业质量标准与检测技术研究所,福建 福州 350003
  • 折叠

摘要

Abstract

A Pb (II)ion-imprinted membrane was prepared by using sodium carboxymethyl cellulose and polyvinyl alcohol.Experimentation was conducted to determine the effectiveness of the membrane in removing the heavy metal from the biogas slurry collected from 3 local pig farms.The results indicated that the membrane had a spongy, gully-like structure with cavities in a size of approximately 0.24 nm similar to that of Pb (II).The hydrophilicity of the surface of the Pb (II)-IIM was significantly improved after the imprint benefiting the affinity and binding of Pb (II)to the membrane loci.The membrane showed a high selectivity in allowing the permeation of lead ions.The infiltration for various metal ions were in the order of:Pb (II)>Zn (II)>Cu (II)>Cd (II)>Co (II).The Pb (II)removal rate by the membrane on the biogas slurry was 93%-95%.The effluent after the filtration met the requirement for environmental protection in the vegetable-producing regions.

关键词

铅离子印迹膜/猪场沼液/重金属铅/选择渗透

Key words

lead ion-imprinted membrane/pig biogas slurry/lead/selective permeation

分类

资源环境

引用本文复制引用

肖艳春,黄婧,林香信,陈彪..去除猪场沼液重金属 Pb(II)的离子印迹膜制备及其应用[J].福建农业学报,2016,31(1):57-62,6.

基金项目

福建省科技计划项目---省属公益类科研院所基本科研专项(2015R1015-9、2015R1015-4、2014R1015-13、2015R1025-5、2014R1025-2);福建省农业科学院青年创新基金项目(2014CX-14,2014CX-13);福建省农业科学院科技下乡“双百”行动项目 ()

福建农业学报

OA北大核心CSTPCD

1008-0384

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