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准东煤流化床气化飞灰的理化特性研究

张玉魁 张海霞 朱治平

燃料化学学报2016,Vol.44Issue(3):305-313,9.
燃料化学学报2016,Vol.44Issue(3):305-313,9.

准东煤流化床气化飞灰的理化特性研究

Physical and chemical properties of fly ash from fluidized bed gasification of Zhundong coal

张玉魁 1张海霞 2朱治平1

作者信息

  • 1. 中国科学院工程热物理研究所,北京 100190
  • 2. 中国科学院大学,北京 100049
  • 折叠

摘要

Abstract

The ash fusionc harca teristics, physical structure, chemical compso itions and gasification reactivity of Zhundong coal ( ZD ) fly ash from fluidized bed gasification were explored by fusion point analyzer, X-ray fluorescence spectrometer ( XRF) , scanning electron microscopy ( SEM) , and therm o-gar vimetric analyzer.The results show that the concentrations of minerals in ZD fly ash, such as SiO2 , Fe2 O3 , Na2 O, CaO, change greatly during gasificatio n process, but the ash fusionet mperature of ZD fly ash is similar to that of ZD.Theresi a wide particle-size distribution in ZD fly ash, which shows a significant bimodal distribution, and a large differecn e of elemental compositions for ZD fly sa h of dif erent partilc e size.The reactivity of ZD fly ash increasesw ith the increaes in gsa ification temperature.Compared with the ZD cah r from pyrolysis, the ZD fly ash has more advancedc arbon crystla line structure, a largre surface ra ea and is relatively rich in meos -pores and macro-pores, wh ich results in a higher gasfi icait on reactivity.

关键词

准东煤/流化床气化/熔融特性/气化反应活性

Key words

Zhundogn coal/lf uidizde bed ag sification/fusion characteristics/gasification reactivity

分类

化学化工

引用本文复制引用

张玉魁,张海霞,朱治平..准东煤流化床气化飞灰的理化特性研究[J].燃料化学学报,2016,44(3):305-313,9.

基金项目

The project was supported by the National Natural Science Foundation of China (21306193).@@@@国家自然科学基金(21306193)项目资助 ()

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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