燃料化学学报2016，Vol.44Issue(3)：328-334,7.
矿物质对桦甸油页岩热解产物影响特性
Effect of mineral matter on product evolution during pyrolysis of Huadian oil shale
摘要
Abstract
The effect of mineral matter on pyrolysis and product evolution of oil shale was studied by GC and FT-IR.Hudian oil shale was treated by sequential washing with HCl and HF/HCl.The results show that carbonate has catalytic effect on conversion of organic carbona nd hydor gen fromKe rogen to shale oil, whichis inhibited by silicate. The H/C atomic ar tio in shael oil increases in both cra bonate-free and silicate-free oil shale. Carbonatee nhances gas yield and inhibits oil yield, while silicate is just opposiet .The cont ents of CO2 and H2 d ecresa e butC O increaes si n both carbonate-fer e and sli icate-freeo il shale.Carbonate can inhibit generation of hydrocarbon in gas product while silicate has catalytci effect on it.All the carbonate and silicta e can increase the length and degree of branchinga liphatic side chains in shla e oil and improve aromatization of the soil d product from shale.关键词
脱矿/油页岩/热解/色谱/红外光谱Key words
demineralizatoi n/oil sha le/pyrolysis/GC/FT-IR分类
能源科技引用本文复制引用
王擎,张宏喜,迟铭书,崔达,许祥成..矿物质对桦甸油页岩热解产物影响特性[J].燃料化学学报,2016,44(3):328-334,7.基金项目
The project was supported by the National Natural Science Foundation ofCh ina （51276034）．@@@@国家自然科学基金（51276034）项目资助 （）
