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氯化亚锡和纳米二氧化硅对PET材料表面亲水性影响

周圣文 方亮 赵欢 吕晓璇 王力

表面技术2016,Vol.45Issue(4):213-217,231,6.
表面技术2016,Vol.45Issue(4):213-217,231,6.DOI:10.16490/j.cnki.issn.1001-3660.2016.04.036

氯化亚锡和纳米二氧化硅对PET材料表面亲水性影响

Effects of SnCl2 and Nano-silica on Hydrophilicity of PET Materials

周圣文 1方亮 1赵欢 1吕晓璇 1王力1

作者信息

  • 1. 山东科技大学 化学与环境工程学院,山东 青岛266590
  • 折叠

摘要

Abstract

Objective To improve the surface hydrophilicity of PET materials. Methods In this paper, highly hydrophilic PET materials were prepared by blending with SnCl2 and then grafting amination-modified nano-silica on the surface of the blended film. The surface properties of PET materials were characterized by static contact angle measurement, Fourier transformed infrared spec-troscopy and atomic force microscopy. Results The results showed that amination-modified nano-silica was successfully grafted on the surface of the SnCl2/PET blended materials. When the content of SnCl2 was 0. 3% in PET materials, the surface contact angle of blending membrane dropped from 98° to 74. 5°. The surface contact angle of PET materials dropped from 74. 5° to 7. 8° after the blending membrane was grafted with amination-modified nano-silica for 20 h, and the hydrophilicity was increased dramatically. The surface contact angle of PET materials increased from 7. 8° to 34. 9°after the grafted membrane was soaked in distilled water for 10 d. Conclusion The surface hydrophilicity of PET materials was improved greatly by blending with SnCl2 and then grafting amina-tion-modified nano-silica.

关键词

PET/亲水性/共混/接枝/改性纳米二氧化硅/氯化亚锡/接触角

Key words

PET/hydrophility/blend/graft/modified nano-silica/SnCl2/contact angle

分类

化学化工

引用本文复制引用

周圣文,方亮,赵欢,吕晓璇,王力..氯化亚锡和纳米二氧化硅对PET材料表面亲水性影响[J].表面技术,2016,45(4):213-217,231,6.

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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