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电喷雾离子源(ESI)中带电液滴的形成与碎裂模拟

黄兆亮 高方园 王伯良 张维冰

高等学校化学学报2016,Vol.37Issue(4):633-637,5.
高等学校化学学报2016,Vol.37Issue(4):633-637,5.DOI:10.7503/cjcu20150812

电喷雾离子源(ESI)中带电液滴的形成与碎裂模拟

Simulation of the Formation and Fission of Charged Droplets in Electrospray Ion Source

黄兆亮 1高方园 2王伯良 1张维冰2

作者信息

  • 1. 南京理工大学化工学院,南京210094
  • 2. 上海市功能性材料化学重点实验室,华东理工大学化学与分子工程学院化学系,上海200237
  • 折叠

摘要

Abstract

The Fluent software was used to simulate the formation and fission of charged droplets in electro-spray ion source based on the transport behavior of liquid in electrospray ion source(ESI) and constructed. The influence of the capillary voltage, ion source temperature and surface tension on droplet size distribution was studied. The results indicate that high capillary voltage, high source temperature, and low surface tension lead to smaller charged droplets and better breakup, which is in consistency with the study in published literatures and the calculation with empirical formula in this work.

关键词

Fluent模拟/电喷雾离子源(ESI)/带电液滴/粒径分布

Key words

Fluent simulation/Electrospray/Charged droplet/Particle size distribution

分类

化学化工

引用本文复制引用

黄兆亮,高方园,王伯良,张维冰..电喷雾离子源(ESI)中带电液滴的形成与碎裂模拟[J].高等学校化学学报,2016,37(4):633-637,5.

基金项目

国家自然科学基金(批准号:21235005)和国家重大仪器设备开发专项(批准号:2012YQ120044)资助.Supported by the National Natural Science Foundation of China(No. 21235005) and the Development of Major National Special Equipment Funding of China(No. 2012YQ120044). (批准号:21235005)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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