高等学校化学学报2016，Vol.37Issue(4)：669-673,5.DOI:10.7503/cjcu20150799
果胶负载钯催化剂的制备及Suzuki反应催化性能
Preparation and Suzuki Reaction Performance of Pectin-supported Palladium Catalyst
摘要
Abstract
To discover new heterogeneous palladium catalyst in organic synthesis, pectin, which was extracted form citrus peel, was used as supporter for the preparation of pectin-supported palladium catalyst. The pectin-supported palladium catalyst was applied to Suzuki cross-coupling reaction between sodium tetraphenylborate and aryl bromides. The results revealed that all four aryl groups of sodium tetraryylborate could be efficiently utilized in the Suzuki cross-coupling reactions in an atom-efficient way in the presence of Et3 N as base in PEG 400/H2 O at 110 ℃ in open air, providing excellent yields of the corresponding functionalized biaryls within 1 h. The present protocol has the advantages highly efficient, high yield, mild condition, short reaction time, as well as the catalyst can be recycled and reused.关键词
果胶负载钯/Suzuki反应/四苯硼钠/溴代芳烃Key words
Pectin supported-Pd/Suzuki reaction/Sodium tetraphenylborate/Aryl bromide分类
化学化工引用本文复制引用
周文俊,周宇,张霞忠,曾彬..果胶负载钯催化剂的制备及Suzuki反应催化性能[J].高等学校化学学报,2016,37(4):669-673,5.基金项目
四川省教育厅重大成果转化项目(批准号: 12ZZ012)、 四川省教育厅自然科学青年基金项目(批准号: 12ZB074, 13ZB0002)和内江师范学院博士科研启动费项目(批准号:2012B05)资助. Supported by the Sichuan Province Education Office Fostering Projects, China(No. 12ZZ012), the Youth Found of Sichuan Province Education Office, China(Nos. 12ZB074, 13ZB0002) and the Startup Foundation of Ph. D. Scientific Research of Neijiang Normal University, China(No. 2012B05). （批准号: 12ZZ012）
