化工进展2016，Vol.35Issue(3)：793-800,8.DOI:10.16085/j.issn.1000-6613.2016.03.022
乙烯齐聚合成α-烯烃镍配合物催化剂研究进展
Progress of nickel complex catalysts towards ethylene oligomerization forα-olefin
摘要
Abstract
Nickel complexes are important ethylene oligomerization catalysts and have shown good application prospect in the synthesis ofα-olefin due to their high activity,mild reaction conditions and high selectivity. The latest research progress of nickel complex catalysts towards ethylene oligomerization forα-olefin has been reviewed herein. In terms of molecular structure of the ligand,the discussions focus on the research status of imino pyridyl ligand nickel complex catalysts and pyrazole ligand nickel complex catalysts,including the influence of the ligand structure,substitution group effect and process conditions on the catalytic activity and product distribution. At the same time,the development of other types of ligands,including formazan,phosphine oxazoline,thiophene,dinuclear structure and dendritic ligands is also briefly introduced. The study of the effect of the fine structure of the nickel complexes on the catalytic activity and the selectivity ofα-olefin has important significance for the design of high carbonα-olefin catalyst with the prospect of industrial application.关键词
乙烯齐聚/α-烯烃/催化剂/选择性/活性Key words
ethylene oligomerization/α-olefin/catalyst/selectivity/reactivity分类
化学化工引用本文复制引用
王俊,梁红姣,李翠勤,施伟光..乙烯齐聚合成α-烯烃镍配合物催化剂研究进展[J].化工进展,2016,35(3):793-800,8.基金项目
国家自然科学基金（21576048）、中国石油创新基金（2014D-5006-0503）及东北石油大学青年科学基金（2013NQ130）项目。 （）
