南京林业大学学报（自然科学版）2016，Vol.40Issue(2)：88-94,7.DOI:10.3969/j.issn.1000-2006.2016.02.015
7－芳亚甲基异长叶烷酮类化合物的合成及其紫外吸收特征
Synthesis and ultraviolet absorption characteristics of 7-arylidene-isolongifolanene
摘要
Abstract
A series of 7⁃arylidene⁃isolongifolanone a—j were synthesized by condensation of isolongifolanone with aro⁃matic aldehydes including 4⁃bromobenzaldehyde, 4⁃fluorobenzaldehyde, 3⁃nitrobenzaldehyde, 2,4⁃dichlorobenzaldehyde under catalyzation of potassium tert⁃butoxide. The structures of compounds a—j were identified by means of 1 H NMR, 13 C NMR, GC⁃MS and FT⁃IR, and their ultraviolet absorption characteristics as well as light stabilities were also investi⁃gated. The results showed that compounds a, b, c, d and j exhibited good absorbency as the medium⁃wave ultraviolet ( UVB) type absorbents,and compounds e, f, g, h and i had both functions as long⁃wave ultraviolet ( UVA) and UVB absorbents. The light stability sequence of those compounds was h>g>e>c>a>d>b>f>i>j. The UV absorption intensity was d>i>e>h>g>f>b>c>j>a.关键词
异长叶烷酮/7-芳亚甲基异长叶烷酮/紫外吸收/光稳定性Key words
isolongifolanone/7-arylidene-isolongifolanone/ultraviolet absorption/lightstability分类
化学化工引用本文复制引用
芮坚,徐徐,杨益琴,黄建峰,王石发..7－芳亚甲基异长叶烷酮类化合物的合成及其紫外吸收特征[J].南京林业大学学报（自然科学版）,2016,40(2):88-94,7.基金项目
江苏省高校自然科学研究重大项目（14KJA220001）；国家自然科学基金项目（31170538，31470592）；江苏省生物质能源与材料重点实验室开放基金 （）
