日用化学工业2016，Vol.46Issue(3)：158-161,167,5.DOI:10.13218/j.cnki.csdc.2016.03.008
植物油电化学法合成环氧化合物
Synthesis of vegetable oil epoxides with electrochemical method
摘要
Abstract
Vegetable oil epoxides were synthesized with electrochemical method. The optimum conditions for castor oil epoxidation technology were determinated by L18 (37 )orthogonal test. The starting material castor oil as well as its epoxidized derivatives was characterized and compared by FT-IR and TG analysis. Experimental results showed that the optimum conditions are:reaction time,4 h;pH value,6. 5;reaction temperature,30 ℃;oxygen flow rate,3 cm3/s;current density,0. 3 A/cm2;molar ratio of castor oil double bonds to HCOOH,8;and catalyst (0. 1 mol/L hydrochloric acid)dosage,0. 3 mL. Under such conditions,the relative yield of epoxidized castor oil achieves 53. 7%. The FT-IR spectra indicated that new material containing -C-O-C-group was produced accompanying with the disappearance of -C=C- group;and TG analysis indicated that the thermal stability of - C - O - C - groups is stronger than that of - C = C - groups under certain conditions. Such results suggested that synthesis of vegetable oil epoxides with electrochemical method is feasible. In addition,similar tests for using of soybean oil,corn oil and peanut oil were also done.关键词
植物油/电化学合成法/环氧化/不饱和脂肪酸Key words
vegetable oil/electrochemical synthesis/epoxidation/unsaturated fatty acid分类
化学化工引用本文复制引用
田美凤,李万捷,梁镇海..植物油电化学法合成环氧化合物[J].日用化学工业,2016,46(3):158-161,167,5.基金项目
国家自然科学基金委员会和神华集团有限责任公司联合资助项目（U1261103）；国家自然科学基金资助项目 （）
