化工学报2016，Vol.67Issue(4)：1098-1102,5.DOI:10.11949/j.issn.0438-1157.20141904
乙酸乙酯-间苯二酚-酸性盐水液液相平衡测定及关联
Measurement and correlation of liquid-liquid equilibrium data for acetic ether-resorcinol-acid brine system
摘要
Abstract
Acetic ether was used as solvent for extraction of resorcinol under the environment of acid brine. Liquid-liquid equilibrium (LLE) data of acetic ether-resorcinol-acid brine quasi ternary system were determined at atmospheric pressure (101.33 kPa) and 313 K with the equilibrium method. The experimental data showed that the mutual solubility of acetic ether and water was increased with increasing resorcinol which reduced the extraction effect of the acetic ether on resorcinol, while the solubility of acetic ether in water was reduced in the existence of ammonium sulphate which was good for the extraction process. The experimental data were correlated with NRTL model and parameters were obtained. The calculation results agreed well with the experimental data, indicating that the models used were suitable for the system. The model also provided data for the design of extraction process ofm-phenylenediamine hydrolysis for joint production of resorcinol withm-aminophenol.关键词
间苯二酚/乙酸乙酯/液液平衡/NRTL模型/溶剂萃取Key words
resorcinol/acetic ether/liquid-liquid equilibrium/NRTL model/solvent extraction分类
化学化工引用本文复制引用
孔令启,王渊朴,曹婺,李玉刚..乙酸乙酯-间苯二酚-酸性盐水液液相平衡测定及关联[J].化工学报,2016,67(4):1098-1102,5.基金项目
山东省自然科学基金项目（ZR2011BL010）。@@@@supported by the Natural Science Foundation of Shandong Province (ZR2011BL010) （ZR2011BL010）
