化工学报2016，Vol.67Issue(4)：1324-1332,9.DOI:10.11949/j.issn.0438-1157.20151370
NaOH浓度对苯选择加氢制环己烯Ru-Zn催化剂性能的影响
Effect of NaOH concentration on performance of Ru-Zn catalyst for selective hydrogenation of benzene to cyclohexene
摘要
Abstract
Ru-Zn catalysts were prepared by the co-precipitation method, and the effect of the different NaOH concentration as precipitant and reduction medium on the performance of Ru-Zn catalyst for selective hydrogenation of benzene to cyclohexene was investigated. The catalysts were characterized by X-ray diffraction (XRD), N2 physisorption (BET), X-ray fluorescene (XRF) and transmission electron micrograph (TEM). It was found that the concentration of NaOH could modify the Zn contents, particle size and pore diameter, and then affect the performance of Ru-Zn catalysts. The Ru-Zn catalyst prepared with the NaOH concentration of 15% gave a high cyclohexene yield of 61.5%. Moreover, this catalyst exhibited the excellent reusability.关键词
苯/加氢/钌/催化剂/沉淀剂/还原介质Key words
benzene/hydrogenation/ruthenium/catalyst/precipitant/reduction medium分类
资源环境引用本文复制引用
孙海杰,陈秀丽,黄振旭,刘仲毅,刘寿长..NaOH浓度对苯选择加氢制环己烯Ru-Zn催化剂性能的影响[J].化工学报,2016,67(4):1324-1332,9.基金项目
国家自然科学基金项目（21273205，U1304204）；河南省高等学校重点科研项目(16A150025)；河南省科技攻关重点项目（162102210333）。@@@@supported by the National Natural Science Foundation of China (21273205, U1304204), the Key Scientific Research Project of Henan Province(16A150025) and the Key Scientific and Technological Research Project of Henan Province(162102210333) （16A150025）
