天津工业大学学报2016,Vol.35Issue(2):1-6,6.DOI:10.3969/j.issn.1671-024x.2016.02.001
聚二乙二醇十六烷基醚单丙烯酸酯/氧化石墨烯复合定型相变材料的制备及表征
Preparation and characterization of poly(diethylene glycol hexadecyl ether acrylate)/graphene oxide composite shape-stabilized phase change materials
摘要
Abstract
Poly (diethylene glycol hexadecyl ether acrylate)/graphene oxide (PC16E2AC/GO) composite-shape stabilized phase change materials was prepared by the solution blending method. The morphology and structure, phase change behavior and thermal stability of PC16E2AC/GO were characterized by scanning electron microscope (SEM), differential scanning calorimetry (DSC) and thermal gravimetric analysis (TG). The results show that the addition of GO can significantly improve the shape stability of PC16E2AC. When the content of GO is 5%, the PC16E2AC/GO composite material has high heat enthalpy, good thermal stability and thermal stability. The composite phase change materials with 5%GO appears can maintain a good shape above the melting temperature of PC16E2AC and no leakage of PC16E2AC appears after 100 min treatment at 85℃. In addition, good thermal cycling stability is possessed which is approved by 300 times of hot and cold cycle tests.关键词
聚合物相变材料/定型相变材料/梳状聚合物/GO改性Key words
polymer phase change materials/shape-stabilized phase change materials/comb like polymer/GO modifica-tion分类
化学化工引用本文复制引用
张兴祥,李树芹,陈赛,裴东方..聚二乙二醇十六烷基醚单丙烯酸酯/氧化石墨烯复合定型相变材料的制备及表征[J].天津工业大学学报,2016,35(2):1-6,6.基金项目
国家自然科学基金资助项目 ()