化工进展2016，Vol.35Issue(5)：1377-1386,10.DOI:10.16085/j.issn.1000-6613.2016.05.017
生物质基含氧化合物化学催化法制备长链烷烃的研究进展
Advances on chemocatalytic transformation of biomass-derived oxygenated compounds into long-chain hydrocarbons
摘要
Abstract
The renewable transportation fuels,such as mixed alcohols,hydrocarbon fuels,bio-diesel, can be produced from biomass resource. Hydrocarbon fuels have become the key items in the development of new generation biofuels,for its excellent utilization property compared with the oxygen-containing fuels. This review focuses on the formation of new generation biofuels with more than 8 carbon atoms,derived from simple sugars through a series of catalytic reactions. Oxygenated compounds with five or six carbon atoms are converted to fuel precursors which have appropriate carbon atoms compared with petrol-based transportation fuels,then the oxygenation-atoms are removed efficiently through different reaction strategies and catalytic technologies. The corresponding catalysts,reaction conditions,chemistries for the selective conversion are summarized in this review. And the advantages and problems of different reaction routes have been evaluated. In the last,the suggestions are given on the industrialization of producing transportation fuels from lignocellulose through chemocatalytic processes.关键词
生物质/C-C键扩链/加氢脱氧/长链烷烃Key words
biomass/C-C coupling/hydrodeoxygenation/long-chain hydrocarbon分类
能源科技引用本文复制引用
闫少康,孙绍晖,马春松,孙培勤,陈俊武..生物质基含氧化合物化学催化法制备长链烷烃的研究进展[J].化工进展,2016,35(5):1377-1386,10.基金项目
国家自然科学基金项目（21376226）。 （）
