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锂离子电池电解液负极成膜添加剂的研究进展

周丹 梁风 姚耀春

化工进展2016,Vol.35Issue(5):1477-1483,7.
化工进展2016,Vol.35Issue(5):1477-1483,7.DOI:10.16085/j.issn.1000-6613.2016.05.031

锂离子电池电解液负极成膜添加剂的研究进展

Research progress of negative film-forming additives in electrolyte for Li-ion batteries

周丹 1梁风 1姚耀春1

作者信息

  • 1. 昆明理工大学真空国家工程实验室,云南省有色金属真空冶金重点实验室,省部共建复杂有色金属资源清洁利用国家重点实验室,云南 昆明650093
  • 折叠

摘要

Abstract

Forming a stable solid electrolyte interface film (SEI film) is the key to solve the compatibility between lithium ion battery electrode material and electrolyte. Therefore,the research of high quality anode film-forming additive in electrolyte for lithium ion battery attracts much attention. The principle of film-forming additives for organic electrolyte in Li-ion batteries was reviewed. The research status of a variety of additives was particularly introduced. The recent progress on negative film-forming additives was reviewed in detail,from the perspectives of film formation mechanisms and quantum calculation. The main problem was how to select more suitable and efficient film-forming additives. In addition,the possible trends in this area were proposed:①Understanding the mechanism of additive reacting with the electrolyte,especially for the negative film forming additive which has minimum side effects for lithium ion battery;②Combining two or more additives together to compensate the deficiencies of one additive;③Increasing the solubility of inorganic film-forming additives in the electrolyte.

关键词

锂离子电池/电解质/成膜添加剂/固态电解质界面膜(SEI膜)

Key words

Li-ion battery/electrolytes/film-forming additives/solid electrolyte interface (SEI)

分类

化学化工

引用本文复制引用

周丹,梁风,姚耀春..锂离子电池电解液负极成膜添加剂的研究进展[J].化工进展,2016,35(5):1477-1483,7.

基金项目

国家自然科学基金(51364021)、教育部“创新团队发展计划”(IRT1250)及云南省自然科学基金(2014FA025)项目。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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