化工进展2016,Vol.35Issue(5):1477-1483,7.DOI:10.16085/j.issn.1000-6613.2016.05.031
锂离子电池电解液负极成膜添加剂的研究进展
Research progress of negative film-forming additives in electrolyte for Li-ion batteries
摘要
Abstract
Forming a stable solid electrolyte interface film (SEI film) is the key to solve the compatibility between lithium ion battery electrode material and electrolyte. Therefore,the research of high quality anode film-forming additive in electrolyte for lithium ion battery attracts much attention. The principle of film-forming additives for organic electrolyte in Li-ion batteries was reviewed. The research status of a variety of additives was particularly introduced. The recent progress on negative film-forming additives was reviewed in detail,from the perspectives of film formation mechanisms and quantum calculation. The main problem was how to select more suitable and efficient film-forming additives. In addition,the possible trends in this area were proposed:①Understanding the mechanism of additive reacting with the electrolyte,especially for the negative film forming additive which has minimum side effects for lithium ion battery;②Combining two or more additives together to compensate the deficiencies of one additive;③Increasing the solubility of inorganic film-forming additives in the electrolyte.关键词
锂离子电池/电解质/成膜添加剂/固态电解质界面膜(SEI膜)Key words
Li-ion battery/electrolytes/film-forming additives/solid electrolyte interface (SEI)分类
化学化工引用本文复制引用
周丹,梁风,姚耀春..锂离子电池电解液负极成膜添加剂的研究进展[J].化工进展,2016,35(5):1477-1483,7.基金项目
国家自然科学基金(51364021)、教育部“创新团队发展计划”(IRT1250)及云南省自然科学基金(2014FA025)项目。 ()