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低阶煤温和液化-炭化耦合转化过程及产物性质

庄德旺 吴诗勇 尤全 黄胜 尚建选 闵小建 郑化安 吴幼青

燃料化学学报2016,Vol.44Issue(5):528-533,6.
燃料化学学报2016,Vol.44Issue(5):528-533,6.

低阶煤温和液化-炭化耦合转化过程及产物性质

Low rank coal mild liquefaction coupled with carbonization and its products

庄德旺 1吴诗勇 1尤全 2黄胜 1尚建选 1闵小建 2郑化安 3吴幼青3

作者信息

  • 1. 华东理工大学 能源化工系,上海 200237
  • 2. 华东理工大学 煤气化及能源化工教育部重点实验室,上海 200237
  • 3. 陕西煤业化工技术研究院有限责任公司,陕西 西安 710070
  • 折叠

摘要

Abstract

The distribution of products was preliminarily studied based on a process of low rank coal mild liquefaction at 390-450℃ coupled with carbonization. The characteristics of liquid product and semi-coke were analyzed. The results showed that the organic liquid product yield is 23. 44%-33. 26% ( daf, coal) and the semi-coke yield is 49. 56%-68. 72% (daf, coal). The water content of liquid product is 1. 30%-2. 49%. The n-hexane soluble content of organic liquid product is higher than 98 . 95% with no solid particles in liquid product. The carbon content of semi-coke obtained is 87. 87%-93. 45% ( daf), some semi-cokes have the characteristics of strong caking property. There is a close correlation between caking property and asphaltene content of semi-coke.

关键词

低阶煤/温和液化-炭化耦合/液相产物/半焦/黏结性

Key words

low rank coal/mild liquefaction coupled with carbonization/liquid product/semi-coke/caking property

分类

化学化工

引用本文复制引用

庄德旺,吴诗勇,尤全,黄胜,尚建选,闵小建,郑化安,吴幼青..低阶煤温和液化-炭化耦合转化过程及产物性质[J].燃料化学学报,2016,44(5):528-533,6.

基金项目

The project was supported by the National Natural Science Foundation of China (21476079,21476080) and the Fundamental Research Funds for the Central Universities (WB1414014).国家自然科学基金(21476079,21476080)和中央高校基本业务费(WB1414014)项目资助 (21476079,21476080)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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