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高效液相色谱法测定3种水溶性荧光增白剂

魏峰 吴际萍 殷祥刚 葛明桥

印染助剂2016,Vol.33Issue(5):58-60,3.
印染助剂2016,Vol.33Issue(5):58-60,3.

高效液相色谱法测定3种水溶性荧光增白剂

Determination of three fluorescent whitening agents by liquid chromatography

魏峰 1吴际萍 2殷祥刚 3葛明桥4

作者信息

  • 1. 无锡出入境检验检疫局,江苏无锡 214101
  • 2. 江南大学生态纺织教育部重点实验室,江苏无锡 214122
  • 3. 江苏出入境检验检疫局纺织工业产品检测中心,江苏无锡 214101
  • 4. 江苏出入境检验检疫局纺织工业产品检测中心,江苏无锡 214101
  • 折叠

摘要

Abstract

A new method was investigated to determine three fluorescent whitening agents by liquid chromatography (DAD). The fluorescent whitening agents were analyzed by Eclipse Plus C18 column (4.6 mm ×100 mm, 3.5 μm), employing acetonitrile- water as the mobile phase in a gradient elution mode. Meanwhile, the detection wavelength was 348 nm. The results showed that there was good linear relationship in the range of 5~1 000 mg/L for BA (r=0.999 7); while in the range of 1~1 000 mg/L for CXT (r=0.999 9). BBU also had good linear relationship in the range of 50~1 000 mg/L (r=0.999 9). The RSD values of three fluorescent whitening agents were 2.82%, 1.71% and 1.48% (n=6), respectively. This method was precise and had good reproducibility, accurate and reliable data.

关键词

高效液相色谱/荧光增白剂/BA/CXT/BBU

Key words

HPLC/fluorescent whitening agent/BA/CXT/BBU

分类

化学化工

引用本文复制引用

魏峰,吴际萍,殷祥刚,葛明桥..高效液相色谱法测定3种水溶性荧光增白剂[J].印染助剂,2016,33(5):58-60,3.

基金项目

江苏省博士后科研资助计划项目 ()

印染助剂

OA北大核心CSTPCD

1004-0439

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