化工进展2016,Vol.35Issue(6):1587-1605,19.DOI:10.16085/j.issn.1000-6613.2016.06.002
离子液体萃取分离有机物研究进展
Progress in ionic liquids for extraction of organic compounds
摘要
Abstract
Ionic liquids are described as “green solvents” since there is a large degree of cation/anion combinations which make them with the possibility of tuning their properties,as well as their very low volatility. Ionic liquids have been widely used in catalysis,separation and electrochemistry. Thereinto, ionic liquids have been regarded as an efficient extractant for extraction organic compounds. In this work,the ionic liquids used in the separate of hydrocarbon compounds,organic acids,alcohols, phenols and nature compounds by extraction were summarized and reviewed. The mechanism of the ionic liquids extraction process and the effect of extraction conditions were discussed in detail. It was concluded that the strong hydrogen bond,π-π,van der Waals and electrostatic interactions between ionic liquids and solute molecule make ionic liquids be potential solvents to replace some conventional organic solvents for the extractive separation of organic compounds. Meanwhile,the high viscosity and high costs as well as the recovery of the ionic liquids after extraction process could limit the industrial utilization of ionic liquids,and thus it is still an urgent task.关键词
离子液体/萃取/碳氢化合物/有机酸/醇/酚类化合物/天然化合物Key words
ionic liquids/extraction/hydrocarbons/organic acids/alcohol/phenolic compounds/nature compounds分类
化学化工引用本文复制引用
张香平,白银鸽,闫瑞一,高红帅..离子液体萃取分离有机物研究进展[J].化工进展,2016,35(6):1587-1605,19.基金项目
国家杰出青年科学基金(21425625)及International S&T Cooperation Program of China(2014DFA61670)项目。 ()