大学化学2016，Vol.31Issue(6)：1-6,6.DOI:10.3866/PKU.DXHX201508003
羧基导向C-H官能团化/脱羧偶联反应研究进展
Carboxyl-Directed C-H Functionalization and Subsequent Decarboxylative Coupling Reactions of Aromatic Acids
摘要
Abstract
Employing ortho or papa-substituted benzoic acids as starting materials, meta-substituted aromatic compounds, which are much more difficult to be prepared by the traditional methods, can be generated via an ortho C―H functionalization directed by carboxyl and subsequent ipso decarboxylation. In these reactions, carboxyl acts as the function of traceless-directing group. This paper reviews the recent progress in the transition-metal-catalyzed decarboxylative coupling reactions of aromatic acids to construct C―C and C―heteroatom bonds with carboxyl as the traceless-directing group.关键词
芳香羧酸/脱羧偶联/过渡金属催化/C-H官能团化/羧基导向Key words
Aromatic carboxylic acids/Decarboxylative coupling/Transition-metal-catalyzed/C-H Functionalization/Carboxyl-directing分类
化学化工引用本文复制引用
石先莹,刘课艳..羧基导向C-H官能团化/脱羧偶联反应研究进展[J].大学化学,2016,31(6):1-6,6.基金项目
中央高校基本科研业务费专项资金项目(GK201503030) （GK201503030）
