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Co-Ni-ZrO2/活性炭催化CH4-CO2重整性能研究

苏爱廷 张国杰 屈江文 郝兰霞 贾永

天然气化工(C1化学与化工)2016,Vol.41Issue(3):24-29,6.
天然气化工(C1化学与化工)2016,Vol.41Issue(3):24-29,6.

Co-Ni-ZrO2/活性炭催化CH4-CO2重整性能研究

Carbon dioxide reforming of methane over Co-Ni-ZrO2/AC catalyst

苏爱廷 1张国杰 1屈江文 1郝兰霞 1贾永1

作者信息

  • 1. 太原理工大学 山西省煤科学与技术重点实验室-省部共建国家重点实验室培育基地,山西 太原 030024
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摘要

Abstract

Series of Co-Ni/activated carbon (AC) with different mass ratio of Co/Ni, Co-ZrO2/AC and Co-Ni-ZrO2/AC catalysts were prepared by co-impregnation, and characterized by XRD, SEM and BET. Their performances for carbon dioxide reforming of methane to syngas were investigated in a fixed bed reactor. The results show that the 8Co-4Ni-ZrO2/AC had larger surface area, smaller metal particles and better metal dispersion, exhibiting excellent catalytic activity and stability, which could obtain high methane and carbon dioxide conversions of both more than 95% under 850° C, and no obvious deactivation was observed in 1900 min.

关键词

甲烷二氧化碳重整/Co-Ni-ZrO2/AC催化剂/合成气

Key words

methane/carbon dioxide reforming/Co-Ni-ZrO2/AC catalyst/syngas

分类

化学化工

引用本文复制引用

苏爱廷,张国杰,屈江文,郝兰霞,贾永..Co-Ni-ZrO2/活性炭催化CH4-CO2重整性能研究[J].天然气化工(C1化学与化工),2016,41(3):24-29,6.

基金项目

国家自然科学基金(21006066和21376003)和山西省高等学校创新人才支持计划资助。 ()

天然气化工(C1化学与化工)

OA北大核心CSCDCSTPCD

1001-9219

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