天然气化工（C1化学与化工）2016，Vol.41Issue(3)：30-36,7.
反应条件对CO甲烷化反应平衡及催化剂性能的影响
Effect of reaction conditions on CO methanation thermodynamic equilibrium and catalyst performance
李鑫 1韩文锋 1魏雪梅 1王真真 1刘化章1
作者信息
- 1. 浙江工业大学工业催化研究所，浙江 杭州 310014
- 折叠
摘要
Abstract
A thermodynamic analysis about the effects of temperature, pressure, and the composition of feed gas on CO metha-nation was carried out. The results indicate that low temperature, high pressure and a high H 2/CO molar ratio are favorable for the conversion of CO and CH4 selectivity. It was found that carbon deposition can be reduced by increasing reaction pressure, H2/CO mo-lar ratio and introducing steam into the feed gas. In addition, the impact of reaction conditions and composition of the feed gas on the performance of Ni-based catalysts were investigated experimentally. Experimental results show that the catalytic performance and the carbon deposition on the surface of catalysts were significantly affected by the reaction parameters, which is substantially consistent with thermodynamic analysis.关键词
CO/甲烷化/热力学分析/积炭条件Key words
carbon monoxide/methanation/thermodynamic analysis/carbon deposition condition分类
化学化工引用本文复制引用
李鑫,韩文锋,魏雪梅,王真真,刘化章..反应条件对CO甲烷化反应平衡及催化剂性能的影响[J].天然气化工（C1化学与化工）,2016,41(3):30-36,7.
