天然气化工（C1化学与化工）2016，Vol.41Issue(3)：58-61,4.
大孔α-Al2O3载体制备及其在制备CO偶联反应催化剂中的应用
Preparation of macroporousα-Al2O3 support and its application in preparing catalyst for CO coupling reaction
唐先智 1李虎 1罗曼 1肖文德1
作者信息
- 1. 上海交通大学化学化工学院，上海 200240
- 折叠
摘要
Abstract
Macroporous α-Al2O3 supports were prepared by using the γ-Al2O3 as raw material, washing it with dilute nitric acid, impregnating the washed γ-Al2O3 with NH4F and then calcining it in the muffle furnace. The samples were characterized by DTG, XRD, SEM and mercury intrusion method. Results show that the sample calcinated under 1050℃ had high purity of α-Al2O3 crystal, high crystallinity, uniform pore size distribution with a average pore size of 2066nm. Furthermore, the α-Al2O3 supported Pd catalyst was prepared and used for CO coupling to produce dimethyl oxalate, over which the conversion of CO could reach 89.0% with a se-lectivity to dimethyl oxalate of 97.6%.关键词
大孔α-氧化铝/载体/钯/CO偶联反应/草酸二甲酯Key words
macroporousα-alumina/support/Pd/CO coupling reaction/dimethyl oxalate分类
化学化工引用本文复制引用
唐先智,李虎,罗曼,肖文德..大孔α-Al2O3载体制备及其在制备CO偶联反应催化剂中的应用[J].天然气化工（C1化学与化工）,2016,41(3):58-61,4.
