中南大学学报(自然科学版)2016,Vol.47Issue(6):2100-2109,10.DOI:10.11817/j.issn.1672-7207.2016.06.038
淮南地区石炭-二叠系泥页岩有机地球化学特征
Organic geochemical characteristics of Carboniferous-Permian mud shale from Huainan area
摘要
Abstract
The organic geochemical characteristics of Carboniferous—Permian mud shale in Huainan area were comprehensively studied, by means of systemic sampling, and petroleum geochemical testing methods such as organic carbon analysis, rock pyrolysis analysis, measurement of vitrinite reflectance, identification of maceral in kerogen and kerogen type, and carbon isotope of kerogen analysis. The results show that the average organic carbon mass fraction in mud shale from Taiyuan formation is 2.08%, the average organic carbon mass fraction in mud shale from Shanxi formation is 2.58%, the average organic carbon mass fraction in mud shale from Lower Shihezi formation is 1.07%, the average organic carbon mass fraction in mud shale from Upper Shihezi formation is 0.57%, and the average organic carbon mass fraction in mud shale from Sunjiagou formation is 0.12%. The organic matter type of Carboniferous—Permian mud shale is mainly typeⅡ2. Vitrinite reflectance Ro of mud shale samples from the studied area is all higher than 0.7%, and the maximal rock pyrolysis temperatures of mud shale from Taiyuan formation, Shanxi formation and Lower Shihezi formation are above 435℃, which indicates organic matter in hydrocarbon source rocks mostly achieves mature:high mature stage of evolution. The contrast analysis results suggest Taiyuan formation, Shanxi formation and Lower Shihezi formation of Carboniferous—Permian are favorable formation for shale gas exploration because of their higher organic matter abundance, good hydrocarbon generation potential and relative high thermal evolution degree of organic matter.关键词
淮南地区/石炭-二叠系/泥页岩/有机地球化学/页岩气Key words
Huainan area/Carboniferous-Permian/mud shale/organic geochemistry/shale gas分类
能源科技引用本文复制引用
刘会虎,胡宝林,薛俊华,徐宏杰,张文永,郑凯歌,兰天贺,任波..淮南地区石炭-二叠系泥页岩有机地球化学特征[J].中南大学学报(自然科学版),2016,47(6):2100-2109,10.基金项目
国家自然科学基金资助项目(41302129,41402140);山西省煤层气联合研究基金资助项目(2012012008);安徽省国土资源厅公益性项目(2012-g-17);安徽省自然科学基金资助项目(1408085QE88)(Projects(41302121,41402140) supported by the National Natural Science Foundation of China (41302129,41402140)
Project(2012012008) supported by the Shanxi Province United Research Funding of Coalbed Methane (2012012008)
Project(2012-g-17) supported by the Commonweal Project from Department of Land and Source in Anhui Province (2012-g-17)
Project(1408085QE88) supported by the Natural Science Foundation of Anhui Province) (1408085QE88)